1.Open the Active Directory Users And Computers console.
2.Navigate to the organizational unit wherein the new contact should reside.
3.Select the organizational unit.
4.Click the Action menu and select New and then Contact.
5.Provide the details for the new contact and click Next.
6.On the Email page, provide the alias for the contact.
7.Select the Create an Exchange Email Address checkbox so that an email address is created for the new contact.
8.Click Modify.
9.Select the SMTP Address option.
10.Provide the fully qualified Internet email address that should be used for the new contact.
11.To override the default Internet mail message formats, click the Advanced tab.
12.Click OK.
13.Click Next and then click Finish.
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